Analysis of the Raman Shifts of Gases Dissolved in Transformer Oil Based on the Density Functional Theory

CHEN Xingang; YANG Dingkun; LI Song; NI Zhi; TAN Hao; TAN Yumiao; MA Jun

doi:10.13296/j.1001-1609.hva.2017.04.019

您当前的位置：

首页 >

文章列表页 >

Analysis of the Raman Shifts of Gases Dissolved in Transformer Oil Based on the Density Functional Theory

更新时间：2025-04-26

- Analysis of the Raman Shifts of Gases Dissolved in Transformer Oil Based on the Density Functional Theory
- High VoltageApparatus Vol. 53, Issue 4, Pages: 116-121(2017)
- 作者机构：
  
  1. 重庆理工大学
  2. 重庆大学输配电装备及系统安全与新技术国家重点实验室
  3. 3. 重庆市能源互联网工程技术研究中心
  4. 重庆鲁能开发(集团)有限公司
- 作者简介：
- 基金信息：
- DOI：10.13296/j.1001-1609.hva.2017.04.019
  CLC： TM41
- Published：2017
- 稿件说明：
移动端阅览
[1]陈新岗,杨定坤,李松,倪志,谭昊,谭毓苗,马骏.基于密度泛函理论的油中溶解气体拉曼特征频谱分析[J].高压电器,2017,53(04):116-121.

CHEN Xingang, YANG Dingkun, LI Song, et al. Analysis of the Raman Shifts of Gases Dissolved in Transformer Oil Based on the Density Functional Theory[J]. High voltageapparatus, 2017, 53(4): 116-121.
[1]陈新岗,杨定坤,李松,倪志,谭昊,谭毓苗,马骏.基于密度泛函理论的油中溶解气体拉曼特征频谱分析[J].高压电器,2017,53(04):116-121. DOI： 10.13296/j.1001-1609.hva.2017.04.019.

CHEN Xingang, YANG Dingkun, LI Song, et al. Analysis of the Raman Shifts of Gases Dissolved in Transformer Oil Based on the Density Functional Theory[J]. High voltageapparatus, 2017, 53(4): 116-121. DOI： 10.13296/j.1001-1609.hva.2017.04.019.

摘要

为了准确获取电力变压器的运行状态

对其进行有效的维护

文中针对7种变压器故障气体的拉曼特征频谱选择

建立了基于密度泛函理论（DFT）中B3LYP方法的气体分子构型优化和拉曼频移特征仿真分析

并结合搭建的拉曼实验平台;对相等含量的7种故障气体完成拉曼检测

结合密度泛函理论与实际检测

确定7种故障气体H

、CH

、C

、CO、CO

的特征拉曼频移分别为:4 155、2 924、2 954、1 346、1 976、2 142、1 390 cm

-1

。此结果已将得到故障气体实测拉曼频移与校正拉曼频移偏差率控制在±3%以内

为故障气体种类的快速判别及定量分析打下基础。

Abstract

In order to accurately obtain the running state of power transformers and maintain effectively

the molecular configuration optimization and the simulations of the 7 kinds of fault gases have been done based on the B3LYP method of the density functional theory（DFT）. Combined with the Raman experimental platform

Raman detection of the seven kinds of fault gases is made under the condition that the concentration is the same. According to some certain principles

the Raman shifts of the seven kinds of fault gases（H

） are determined respectively: 4 155、2 924、2 954、1 346、1 976、2 142、1 390 cm

-1

. The observed Raman frequency and the corrected Raman frequency which is obtained by calculations and analysis are compared

and the deviation rate is within ±3%. This lays the foundation for the fast determination of the gases and the quantitative analysis.

关键词

Keywords

references

Views

133

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Visual Dynamic Simulation on the Performance of Puffer Circuit Breaker

Dynamic Simulation of Vacuum Circuit - breaker and Its Improvement

Study of Simulation and Application of Solid State Circuit Breaker

EXPERIMENTAL SIMULATION TECHNOLOGY OF VIRTUAL PROTOTYPE AND ITS APPLICATION IN THE DESIGN OF OPERATING MECHANISM OF VACUUM CIRCUIT BREAKER

SIMULATION STUDY OF MEASURES TO ELIMINATE THE HARMONIC IN A HIGH VOLTAGE ASD

Related Author

陈晓宁

马志瀛

金立军

吴军辉

沈钰

马履中

HUANG Shao-ping

HUAN Xi-ming

Related Institution

西安交通大学

西安交通大学 710049

江苏理工大学

江苏理工大学镇江212013

Dept. of Elec. and Information Eng., Hu’nan Institute of Engineering

⁰